4.1 Article

Gas Seepage-Induced Features in the Hypoxic/Anoxic, Shallow, Marine Environment of Amfilochia Bay, Amvrakikos Gulf (Western Greece)

Journal

GEOSCIENCES
Volume 11, Issue 1, Pages -

Publisher

MDPI
DOI: 10.3390/geosciences11010027

Keywords

pockmarks; gas seepage; hypoxia; anoxia; semi-enclosed gulf; methane

Funding

  1. European Union [226213]
  2. project IDENTIFICATION, CONSEQUENCES AND MANAGEMENT OF THE ANOXIC ZONE OF AMVRAKIKOS GULF (NW GREECE)
  3. EEA [GR02-0010]
  4. Laboratory of Marine Geology & Physical Oceanography, University of Patras

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The study revealed the presence of a gas-induced pockmark group and hypoxic environment in Amfilochia Bay, which is affected by tectonism. Methane isotopic analysis indicated different sources of gases. Geophysical data suggested that the protrusion mound previously thought to be a submarine volcano may be a mud volcano.
Amfilochia Bay (Eastern Amvrakikos Gulf, Western Greece), a complex marine area affected by tectonism, was investigated for seabed seepage manifestations and for possible inter-relationships between shallow gas accumulations and hypoxia. For this purpose, an integrated research methodology that combined geophysical, geochemical, and hydrographic surveys was applied. Marine geophysical and bathymetric surveys led to the discovery of a gas-induced pockmark group in the study area. Oceanographic surveying confirmed that the bay is hypoxic/anoxic below a depth of 15 m (dissolved oxygen from similar to 4 to 60 mu M). Very weak CH4 seepage was detected in correspondence to the pockmark group that seemed to slightly enhance the hypoxic environment locally and close to the seabed, with no effect in shallower waters and the oxycline. Methane isotopic analysis showed variable carbon isotopic composition (from -41 parts per thousand to -86 parts per thousand) which could be either related to differential CH4 oxidation or mixing between microbial and thermogenic gas. However, the pathway of degassing is clearly related to the fault-controlled pockmark group. A protrusion mound, which has erroneously been reported as a submarine volcano since 1876, could be the result of mud volcanism based on the geophysical data of this study.

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