4.7 Article

Highly stable zinc metal anode enabled by oxygen functional groups for advanced Zn-ion supercapacitors

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 4, Pages 528-531

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07526d

Keywords

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Funding

  1. National Key Research and Development Program of China [2018YFC 1901605]
  2. National Natural Science Foundation of China [52004338]
  3. Hunan Provincial Natural Science Foundation of China [2020JJ5696]
  4. Guangdong Provincial Department of Natural Resources [2020-011]
  5. characteristic application discipline of material science and engineering in Hunan province (Hunan Provincial Education Department NoticeGrants) [[2018]469]

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Konjac glucomannan has been designed to enhance Zn reversibility, with active sites redistributing Zn2+ concentration field to enable uniform Zn deposition and cycling stability in Zn-ion supercapacitors.
Konjac glucomannan (KGM) featuring abundant oxygen functional groups has been elaborately designed to enhance Zn reversibility. Importantly, -OH and C=O groups as active sites could redistribute the Zn2+ concentration field and modulate the plating/stripping rate, further enabling uniformZn deposition without dendrite growth. The Zn@KGM anode enables an advanced Zn-ion supercapacitor to deliver an impressive rate performance and cycling stability (up to 5000 cycles accompanied by a coulombic efficiency of 99.8%).

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