Journal
NEW JOURNAL OF CHEMISTRY
Volume 45, Issue 2, Pages 993-1000Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj05160h
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Funding
- National Natural Science Foundation of China [21805078]
- Fundamental Research Funds for the Central Universities [531118010086]
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A nanocomposite anode consisting of Sb/Sb2O4/Fe3C anchored on reduced graphene oxide was fabricated for potassium ion batteries, showing a reversible specific capacity of 234 mA h g(-1) at 500 mA g(-1) over 280 cycles. The addition of Fe3C as a catalyst promoted the reversible dissolution of the SEI film, resulting in a long-term cycling performance of 108 mA h g(-1) at 2000 mA g(-1) over 1244 cycles.
The abundant reserves of potassium in the earth's crust and its low K/K+ redox potential (-2.93 V) make potassium ion batteries (PIBs) a potential candidate for next-generation ion batteries. Antimony (Sb) has a high theoretical specific capacity for PIBs, but the pulverization of Sb-based electrodes severely shortens their cycle lifetimes and hinders their use in PIBs. Here, a cage compound precursor-derived Sb/Sb2O4/Fe3C nanocomposite anchored on reduced graphene oxide with uniform distribution is fabricated and used as an anode for PIBs. Benefitting from the high capacity of Sb/Sb2O4 and the catalyst Fe3C that can promote the reversible dissolution of SEI film, the anode delivers a reversible specific capacity of 234 mA h g(-1) at 500 mA g(-1) over 280 cycles and a long-term cycling performance of 108 mA h g(-1) at 2000 mA g(-1) over 1244 cycles.
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