Journal
RSC ADVANCES
Volume 11, Issue 6, Pages 3539-3546Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra10739e
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Funding
- JSPS KAKENHI [JP15K05106]
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The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation, preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives.
The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives.
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