4.6 Article

Marigold micro-flower like NiCo2O4 grown on flexible stainless-steel mesh as an electrode for supercapacitors

Journal

RSC ADVANCES
Volume 11, Issue 6, Pages 3666-3672

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra09524a

Keywords

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Funding

  1. UGC, New Delhi [F1-17.1/2016-17/RGNF-2017-18-SC-MAH-35301/(SA-III/website)]
  2. Shivaji University, Kolhapur [SU/C&U.D. Section/94/1390]

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Nanostructured NiCo2O4 deposited on a flexible stainless-steel mesh in the form of porous marigold micro-flowers showed high specific capacitance and good cyclic stability, making it a promising material for energy storage applications.
Nanostructured NiCo2O4 is a promising material for energy storage systems. Herein, we report the binder-free deposition of porous marigold micro-flower like NiCo2O4 (PNCO) on the flexible stainless-steel mesh (FSSM) as (PNCO@FSSM) electrode by simple chemical bath deposition. The SEM and EDS analysis revealed the marigold micro-flowers like morphology of NiCo2O4 and its elemental composition. The porous nature of the electrode is supported by the BET surface area (100.47 m(2) g(-1)) and BJH pore size diameter (similar to 1.8 nm) analysis. This PNCO@FSSM electrode demonstrated a specific capacitance of 530 F g(-1) at a high current density of 6 mA cm(-2) and revealed 90.5% retention of specific capacitance after 3000 cycles. The asymmetric supercapacitor device NiCo2O4//rGO within a voltage window of 1.4 V delivered a maximum energy density of 41.66 W h kg(-1) at a power density of 3000 W kg(-1). The cyclic stability study of this device revealed 73.33% capacitance retention after 2000 cycles. These results indicate that the porous NiCo2O4 micro-flowers electrode is a promising functional material for the energy storage device.

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