Dual-color emitting Mn2+ ion doped (PEA)2PbBr4 perovskite towards white light-emitting diodes

Two-dimensional (2D) perovskites have become a research hotspot due to their large exciton binding energy and excellent stability. However, it is difficult to achieve longer wavelength emission than blue and green light in the 2D perovskites owing to their wide band gap resulting from their strong quantum confinement. Herein, we demonstrate a simple, efficient and low energy consumption crystallization method at room temperature to synthesize Mn2+ ion doped 2D (PEA)(2)PbBr4 nanocrystals (NCs) with dual-color emission centered at 410 nm from the exciton transition of the host and 600 nm from the d-d transition of Mn2+ ions. The periodic XRD peaks prove the formation of 2D perovskites. It is reassuring that the high PLQY of 54% has been achieved in the Mn2+ ion doped 2D (PEA)(2)PbBr4 NCs. The temperature-dependent and time-resolved spectra illustrate the efficient energy transfer from excitons to Mn2+ dopant ions. The realization of white LEDs with different color temperatures presents an opportunity and prospect for Mn2+ ion doped 2D perovskites in LED application.

Automated summary

Research demonstrates a simple, efficient and low energy consumption crystallization method to synthesize Mn2+ ion doped 2D perovskite nanocrystals with dual-color emission. The high PLQY of 54% has been achieved in the Mn2+ ion doped 2D perovskite nanocrystals. The efficient energy transfer from excitons to Mn2+ dopant ions opens up opportunities for white LEDs in LED applications.