Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 6, Pages 733-736Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07446b
Keywords
-
Categories
Funding
- EPSRC [EP/P002560/1, EP/P001386/1, EP/M0270 15/1]
- ERC [CoG612724, StG851504]
- Royal Society (University Research Fellowship)
- German DFG [SL104/10-1]
- University of Manchester
- University of Stuttgart
- EPSRC [EP/M027015/1, EP/P002560/1, EP/P001386/1] Funding Source: UKRI
Ask authors/readers for more resources
In this study, the synthesis of a lanthanide-(bis)boryloxide complex with idealized D-4h@Dy(iii) point-group symmetry was reported. The complex exhibits single-molecule magnetism with one of the highest energy barriers among six-coordinate lanthanide-SMM systems. The validation of electrostatic model predictions by complex 2Dy informs future design of lanthanide-SMMs.
We report the synthesis of the lanthanide-(bis)boryloxide complex [Dy{OB(NArCH)(2)}(2)(THF)(4)][BPh4] (2Dy, Ar = 2,6-(Pr2C6H3)-C-i), with idealised D-4h@Dy(iii) point-group symmetry. Complex 2Dy exhibits single-molecule magnetism (SMM), with one of the highest energy barriers (U-eff = 1565(298) K) of any six-coordinate lanthanide-SMM. Complex 2Dy validates electrostatic model predictions, informing the future design of lanthanide-SMMs.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
