Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 6, Pages 805-808Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07429b
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qStyPy is a modularly applicable, red-shifted, and self-reporting photodynamic covalent crosslinker that undergoes [2+2] cycloadditions in water upon irradiation with 470 nm light. Its rational design increases hydrophilicity and features broad emission in the far-red/near-infrared regime, making it suitable for biomedical applications.
We present a modularly applicable, red-shifted and self-reporting photodynamic covalent crosslinker, abbreviated qStyPy, that performs [2+2] cycloadditions upon irradiation with 470 nm in water. The rational design of qStyPy increases its hydrophilicity due to a permanent charge and features a broad emission in the far-red/near-infrared regime as a readout for the cycloadduct formation, rendering qStyPy suitable for biomedical applications.
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