4.6 Article

Soft actuators by electrochemical oxidation of liquid metal surfaces

Journal

SOFT MATTER
Volume 17, Issue 7, Pages 1921-1928

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sm01851a

Keywords

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Funding

  1. National Oceanographic Partnership Program (NOPP) [N000141812843]
  2. Office of Naval Research [N00014-18-1-2775]
  3. U.S. Department of Defense (DOD) [N000141812843] Funding Source: U.S. Department of Defense (DOD)

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The surface energy of liquid metals can be controlled through electrochemical methods to create small-scale soft-matter actuators with high power density. By adjusting the surface energy of the liquid metal, the force and shape of the electrochemical soft actuator can be controlled.
The surface energy of liquid metals can be electrochemically controlled over a wide range of values - from near zero to 500 mJ m(-2) - using a low voltage potential (similar to 1 V). This enables the ability to create soft-matter actuators that exhibit a high work density on small scales. We demonstrate that a liquid metal (LM) meniscus wetted between two copper pads can function as an electrochemical soft actuator whose force and shape are controllable by tuning the LM surface energy. Energy minimization models are presented in order to predict the actuator performance as a function of LM droplet and Cu pad dimensions. The results suggest that the electrochemical LM actuator has a unique combination of high work density, biologically-relevant activation frequency, and low operational voltage that stands out from other classes of soft-matter actuators.

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