Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 17, Pages 2132-2135Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00240f
Keywords
-
Categories
Funding
- Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences [RVO: 613 88963]
- Czech Science Foundation [20-13745S, 20-01472S]
- Ministry of Education, Youth and Sports [LTAUSA19120]
- US National Science Foundation [CHE-1905238]
Ask authors/readers for more resources
Solvent-free mechanochemical synthesis was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules. Confirmation of successful formation of individual inclusions was independently confirmed by solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis is an alternative route towards new types of cucurbit[n]uril-guest inclusion complexes.
Solvent-free mechanochemical synthesis (ball-milling) was used to prepare inclusion complexes with cucurbit[7]uril and four model guest molecules (adamantane, adamantyl-1-amine hydrochloride, toluidine hydrochloride, and p-phenylenediamine dihydrochloride). Successful formation of individual inclusions was independently confirmed by one- and two-dimensional solid-state NMR techniques and differential scanning calorimetry. Mechanochemical synthesis represents an alternative path towards new types of cucurbit[n]uriliguest inclusion complexes that are not accessible due to limited solubility of the individual components.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available