Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 11, Pages 1320-1323Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc06755e
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Funding
- Science and Technology Facilities Council via the ISIS Neutron and Muon Facility
- U.S. Department of Energy (DOE) Office of Science, Office of Basic Energy Sciences
- 1851 Royal Commission of the Great Exhibition
- U.S. DOE [DE-AC02-06CH11357]
- Division of Chemistry (CHE), National Science Foundation (NSF) [NSF/CHE-1346572, NSF/CHE-1834750]
- NSF [NSF/DMR-1531283]
- National Council of Science and Technology of Mexico (CONACyT) [217553]
- Cambridge Trust [217553]
- Division of Materials Research (DMR), National Science Foundation (NSF) [NSF/CHE-1346572, NSF/CHE-1834750]
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This study reveals the phenomenon of single-crystal nanooptomechanical transduction under specific conditions of light stimulation, along with the changes in molecular structure that occur during this process.
Single-crystal nanooptomechanical transduction occurs in [Ru(SO2)(NH3)(4)(H2O)]chlorobenzenesulfonate(2), reaching maximal levels within 40 s at 100 K when photostimulated by 505 nm light. Its in situ light-induced crystal structure reveals the molecular origins of this optical actuation: 26.0(3)% of the eta(1)-SO2 ligand photoconverts into an eta(1)-OSO photoisomer which, in turn, induces a 49.6(9)degrees arene ring rotation in its neighbouring counter ion.
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