Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 9, Pages 1129-1132Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc06939f
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Funding
- National Natural Science Foundation of China [21701035, 21531006, 21961004]
- Guangxi Natural Science Foundation [2018GXNSFAA138129, 2018GXNSFBA281085]
- Specific research project of Guangxi for research bases and talents [AD18126005]
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201905]
- China Postdoctoral Science Foundation [2020M670525]
- Guangxi University for Nationalities Graduate Education Innovation Project [gxun-chxzs2019023]
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The bulkiness of the guest molecules influenced the conformation of the ligand, and thus the outcome of the cycloaddition reaction.
The photochemical [2+2] cycloaddition of 3,5-bis-(2-(pyridin-4-yl) vinyl)pyridine (bpvp) in the flexible Cd-based metal-alkene frameworks produced different isomeric photoproducts depending on the auxiliary and guest molecules. The bulkiness of the guest molecules influenced the conformation of the ligand, and thus the outcome of the cycloaddition reaction.
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