4.7 Article

Increasing the activity of the Cu/CuAl2O4/Al2O3 catalyst for the RWGS through preserving the Cu2+ ions

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 9, Pages 1153-1156

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07142k

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Funding

  1. European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program (Starting grant: CATACOAT) [758653]

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By depositing a layer of silica, the catalyst surface of Cu-Al spinet oxide was protected and Cu2+ ions were preserved during the calcination process, forming well-dispersed Cu sites for participation in the reaction.
Cu-Al spinet oxide is a highly active catalyst for CO2 conversion to CO. However, it suffers from low surface area. By depositing a silica layer, we protected the catalyst surface and preserved the Cu2+ ions during the calcination process. These ions form well-dispersed Cu sites which participate in the reaction.

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