Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 9, Pages 1141-1144Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc06638a
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Funding
- JSPS KAKENHI [18K14187]
- Grants-in-Aid for Scientific Research [18K14187] Funding Source: KAKEN
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The study showed that the aromatic donor-acceptor interactions between pyrene and pyromellitic diimide derivatives were stronger in siloxane solvents compared to aliphatic solvents due to the poor solubility of the aromatics in siloxanes.
Solvents with a wide range of polarities, including poly(dimethylsiloxane) and oligo(dimethylsiloxane), were used to evaluate aromatic donor-acceptor interactions between pyrene and pyromellitic diimide derivatives. The donor-acceptor interactions were stronger in siloxane solvents than in aliphatic solvents, possibly because of the poor solubility of the aromatics in siloxanes.
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