Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 12, Pages 1486-1489Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07433k
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Funding
- National Natural Science Foundation of China [21672141]
- Robert A. Welch Foundation [F-0018]
- King Abdullah University of Science and Technology [OSR-2019-CRG-4032]
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The synthesis of pyridazine-bridged expanded rosarin 1 and a reduced precursor, semi-rosarinogen 2, are reported. Both 1 and 2 have distorted structures, as shown by single crystal X-ray diffraction analysis and theoretical calculations. These compounds can differentiate various thiols in organic solvents through species-specific color changes and reaction times.
The synthesis of the pyridazine-bridged expanded rosarin 1 and a reduced precursor, semi-rosarinogen 2, is reported. A single crystal X-ray diffraction analysis of 1 and theoretical calculations show that both 1 and 2 have distorted structures. Expanded rosarin 1 and its precursor 2 can differentiate various thiols in organic solvents by means of species-specific colour changes and reaction times.
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