Journal
MATERIALS TODAY CHEMISTRY
Volume 19, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.mtchem.2020.100414
Keywords
Rapid annealing; modification; Redox reaction; Citric acid; Electrochemistry
Funding
- COI STREAM from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT)
- Shin-Etsu Chemical Co., Ltd. Japan
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The study reveals that carboxyl, anhydride, and phenol groups play essential roles in the redox reaction of multiwall carbon nanotubes, which can be selectively removed by different thermal annealing temperatures. A designed carboxyl/anhydride-rich defective MWCNT shows superior specific areal capacitance, providing valuable information for electrochemical applications in supercapacitors and batteries.
Typical functionalization treatment by strong acid is used to introduce functional groups into/onto the multiwall carbon nanotubes (MWCNTs), to enhance the desired redox activity for electrochemical applications. The influence of various functional groups on the redox of MWCNT has been studied in recent years. Different functional groups on MWCNT can be removed selectively using different thermal annealing temperatures. By this method, it is recognized that carboxyl, anhydride, and phenol groups play essential roles in the redox reaction. A designed carboxyl/anhydride-rich defective MWCNT is fabricated with a superior specific areal capacitance of 34.55 mF/cm(2). These results provide more information for the study of the MWCNTs' electrochemical applications toward supercapacitors and batteries. (C) 2020 Elsevier Ltd. All rights reserved.
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