Journal
DALTON TRANSACTIONS
Volume 50, Issue 5, Pages 1712-1720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt04074f
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Funding
- National Science Foundation [CHE-1664977, CHE-1429195, CHE-1828764]
- NIH, COBRE NIGMS [P20GM103546]
- NSF MRI [CHE-1337908]
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The synthetic, structural, and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(II) 1,3-diketonate complexes show anaerobic retro-Claisen type C-C bond cleavage reactivity exceeding that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.
We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(II) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.
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