Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 14, Pages 1802-1805Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc08041a
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Funding
- NSF of China [21820102006, 91856118, 21435003, 21521004]
- MOE of China through the Program for Changjiang Scholars and Innovative Research Team in University [IRT13036]
- scientific and technological plan project in Xiamen [3502Z20203025]
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In this study, supramolecular helical assembly of bis(N-amidothioureas) containing Br-substitutes with moderate halogen bonding ability in water is reported. The assembly is promoted by stronger hydrophobic interactions, leading to helical polymers exhibiting an unusual negative nonlinear CD-ee dependence.
We report supramolecular helical assembly in water of beta-turn structured bis(N-amidothioureas) containing Br-substitutes of moderate halogen bonding ability, promoted by stronger hydrophobic interaction. The helical polymers show an unusual negative nonlinear CD-ee dependence.
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