4.7 Article

Sandwich shelled TiO2@Co3O4@Co3O4/C hollow spheres as anode materials for lithium ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 14, Pages 1786-1789

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07306g

Keywords

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Funding

  1. National Natural Science Foundation of China [21871005]
  2. Program for Innovative Research Team of Anhui Education Committee
  3. Project for Collaborative Innovation of Anhui Higher Education Institutes

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The hollow sandwich-like TiO2@Co3O4@Co3O4/C composite, synthesized by coating Co3O4 nanosheets and TiO2 particles on Co3O4/C hollow spheres, exhibits excellent lithium storage performance and stability due to its superior structure that combines the advantages of each component with favorable electron-transfer and Li+-diffusion properties.
A sandwich shelled hollow TiO2@Co3O4@Co3O4/C composite is synthesized by consecutive coating of Co3O4 nanosheets and TiO2 particles on Co3O4/C hollow spheres. The composite delivers an excellent lithium storage performance, maintaining 1081.78 mA h g(-1) after 100 cycles at 0.2 A g(-1) and 772.23 mA h g(-1) after 300 cycles at 1 A g(-1), due to its superior structure combining the advantages of each component with favorable electron-transfer, Li+-diffusion properties, and distinguished stability.

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