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Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes

Journal

MENDELEEV COMMUNICATIONS
Volume 31, Issue 1, Pages 1-7

Publisher

ELSEVIER
DOI: 10.1016/j.mencom.2021.01.001

Keywords

rhodium; catalysis; diene; cyclopentadienyl; half-sandwich complexes; ligand structure

Funding

  1. Russian Science Foundation [17-73-20144]
  2. INEOS RAS
  3. Ministry of Science and Higher Education of the Russian Federation
  4. Russian Science Foundation [17-73-20144, 20-73-20027] Funding Source: Russian Science Foundation

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The article focuses on the advantages and limitations of classical and more recent synthetic methods for preparing diene and cyclopentadienyl rhodium halides as catalysts, with a particular emphasis on compounds with chiral ligands.
Diene and cyclopentadienyl rhodium halides are very often used as catalysts for various transformations. Herein we analyze the advantages and limitations of classical and more recent synthetic methods for the preparation of these catalysts with a focus on the compounds with chiral ligands.

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