Journal
MENDELEEV COMMUNICATIONS
Volume 31, Issue 1, Pages 1-7Publisher
ELSEVIER
DOI: 10.1016/j.mencom.2021.01.001
Keywords
rhodium; catalysis; diene; cyclopentadienyl; half-sandwich complexes; ligand structure
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Funding
- Russian Science Foundation [17-73-20144]
- INEOS RAS
- Ministry of Science and Higher Education of the Russian Federation
- Russian Science Foundation [17-73-20144, 20-73-20027] Funding Source: Russian Science Foundation
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The article focuses on the advantages and limitations of classical and more recent synthetic methods for preparing diene and cyclopentadienyl rhodium halides as catalysts, with a particular emphasis on compounds with chiral ligands.
Diene and cyclopentadienyl rhodium halides are very often used as catalysts for various transformations. Herein we analyze the advantages and limitations of classical and more recent synthetic methods for the preparation of these catalysts with a focus on the compounds with chiral ligands.
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