Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 8, Pages 1038-1041Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07307e
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Funding
- CNRS
- Univ. Rennes
- Region Bretagne [18003332, 18003308]
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A new method for photoredox-mediated C-H bond alkylation of 6-aryl-2,2'-bipyridines with N-(acyloxy)phthalimides has been reported, showing excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporated C6'-alkyl group on the photophysical properties of the corresponding (N^C^N) cyclometalated Pt(u) complexes, including chiroptical properties, has been described.
Photoredox-mediated C-H bond alkylation of 6-aryl-2,2'-bipyridines with N-(acyloxy)phthalimides is reported. The reaction exhibits excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporated C6'-alkyl group on the photophysical properties of the corresponding (N<^>N<^>C) cyclometalated Pt(u) complexes is described, including chiroptical properties.
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