3.8 Proceedings Paper

Graphene/epoxy resins: Rheological behavior and morphological analysis by Atomic Force Microscopy (AFM)

Journal

MATERIALS TODAY-PROCEEDINGS
Volume 34, Issue -, Pages 160-163

Publisher

ELSEVIER
DOI: 10.1016/j.matpr.2020.02.139

Keywords

Epoxy resins; Rheology; Atomic Force Microscopy (AFM); Graphene-based nanocomposites; Self-assembled structures; Morphological analysis

Funding

  1. European Union's Horizon 2020 research and innovation programme [760940]

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This study focuses on the rheological properties and morphological features of epoxy composites loaded with two similar graphene-based nanoplatelets, differing in exfoliation degree and concentration of carboxylated groups. The incorporation of GNP56 and GNP60 nanostructures significantly alters the rheological response of the nanofilled resin, showing viscoelastic behavior correlated with the morphology congruent with the difference in exfoliation degree.
This work focuses on the rheological properties and morphological features, assessed by Atomic Force Microscopy (AFM), of epoxy composites loaded with two very similar graphene-based nanoplatelets, i.e. GNP56 and GNP60, differing fundamentally for the exfoliation degree (56% and 60%, respectively) and consequently for the concentration of carboxylated groups on the nanoparticle edges. The incorporation of the GNP56 and GNP60 nanostructures inside the epoxy matrix considerably changes the rheological response of the nanofilled resin. The viscoelastic behavior shown by the graphene-based samples perfectly correlates with the different morphology of the two nanofillers that is congruent with the difference in the exfoliation degree percentage. (C) 2019 Elsevier Ltd. All rights reserved.

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