Degradation characteristics of four major pollutants in chemical pharmaceutical wastewater by Fenton process

Present study deals with the treatment of simulated chemical pharmaceutical wastewater (SCPW) using Fenton oxidation process for the degradation of typical pollutants containing n-butanol, ethyl p-nitrobenzoate, 4, 7dichloroquinoline and ethyl acetoacetate. The effects of operational parameters like the initial pH, H2O2/Fe2+ molar ratio, H2O2 dosage and reaction time on the degradation efficiency of pollutants and biodegradability of SCPW were investigated. The Fenton reaction steps and the removal kinetics of SCPW were analyzed. Finally, the effects of the molecular structure on the degradation efficiency of organics were investigated. The degradation ratio of n-butanol, ethyl acetoacetate, 4, 7-dichloroquinoline, ethyl p-nitrobenzoate and chemical oxygen demand (COD) in SCPW is 56%, 75%, 100%, 78% and 38%, respectively, for conditions of initial pH of 2.5, H2O2/Fe2+ molar ratio of 20, H2O2 dosage of 0.6 Q (Q is the theoretical dosage of Fenton reagent) and reaction time of 30 min. The reaction steps analysis indicated that the biodegradability of SCPW was improved mainly by the oxidation intermediate of pollutants. The kinetics study showed that the removal processes of pollutants and COD were consistent with the second-order kinetic model. Quantum chemical analysis showed that the correlation between the total energy E-RB3LYP and removal kinetic constant K-[RH] was most significant, and E-RB3LYP was negatively correlated with K-[RH]. The results indicated that the higher the total energy of the organics, the more difficult it was to be removed. The findings reported herein are significant to predict the treatment efficiency of pollutants in real pharmaceutical wastewater.

Automated summary

The present study focused on the treatment of simulated chemical pharmaceutical wastewater using the Fenton oxidation process. The effects of operational parameters on the degradation efficiency of pollutants and biodegradability of the wastewater were investigated, and the results showed that the removal processes followed a second-order kinetic model. Quantum chemical analysis revealed a significant correlation between total energy and removal kinetic constant, indicating that higher total energy of organics made them more difficult to be removed. These findings are important for predicting the treatment efficiency of pollutants in real pharmaceutical wastewater.