4.7 Article

Intermetallic Fe6Ge5 formation and decay of a core-shell structure during the oxygen evolution reaction

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 17, Pages 2184-2187

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc08035g

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Funding

  1. Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [EXC 2008/1 - 390540038 - UniSysCat]

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Intermetallic iron germanide (Fe6Ge5) is reported as a novel oxygen evolution reaction (OER) precatalyst with a Tafel slope of 32 mV dec(-1) and an overpotential of 272 mV at 100 mA cm(-2) in alkaline media. Furthermore, the in situ formation of a core-shell like structure that slowly collapses under OER conditions is uncovered.
Herein, we report on intermetallic iron germanide (Fe6Ge5) as a novel oxygen evolution reaction (OER) precatalyst with a Tafel slope of 32 mV dec(-1) and an overpotential of 272 mV at 100 mA cm(-2) in alkaline media. Furthermore, we uncover the in situ formation of a core-shell like structure that slowly collapses under OER conditions.

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