Investigating the impact of exit effects on solute transport in macroporous media

The effect of macropore flow on solute transport has spurred much research over the last forty years. In this study, non-reactive solute transport in water-saturated columns filled with porous media crossed by a macropore was experimentally and numerically investigated. The emphasis was put on the study of exit effects, whose very existence is inherent to the finite size of any experimental column. We specifically investigated the impact of a filter at the column outlet on water flow and solute transport in macroporous systems. Experiments involving breakthrough measurements and magnetic resonance imaging (MRI) showed that solute transport displayed some significant non-unidirectional features, with a strong mass exchange at the interface between the macropore and the matrix. Fluid dynamics and transport simulations indicated that this was due to the non-unidirectional nature of the flow field close to the outlet filter. The flow near the exit of the column was shown to be strongly impacted by the presence of the outlet filter, which acts as a barrier and redistributes water from the macropore to the matrix. This impact was apparent on the breakthrough curves and the MRI images. It was also confirmed by computer simulations and could, if not properly taken into account, impede the accurate inference of the transport properties of macroporous media from breakthrough experiments.

Automated summary

The study investigated the impact of macropore flow on solute transport using experimental and numerical methods. It focused on the effects of exit filters at the column outlet on water flow and solute transport in macroporous systems. Results showed significant non-unidirectional features in solute transport due to the presence of the outlet filter and highlighted the importance of considering its impact on transport properties in macroporous media.