Journal
FUEL
Volume 204, Issue -, Pages 236-242Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2017.05.039
Keywords
Ni/MFA@AIL; Lignite-related model compounds; Catalytic hydroconversion
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Funding
- Fundamental Research Funds for the Central Universities [2017BSCXB26]
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Modified microfiber attapulgite (MFA)-supported nickel was prepared by thermally decomposing nickel tetracarbonyl on MFA modified with an acidic ionic liquid (AIL, 1-sulfobuty1-3-methylimidazolium trifluoromethanesulfonate). It was characterized with multiple instruments and used for catalyzing hydroconversion of lignite-related model compounds (LRMCs) oxydibenzene, benzyloxybenzene, and oxybis (methylene)dibenzene. The results indicate that Ni-15%/MFA@AIL effectively catalyzes hydroconversion of the LRMCs to afford cyclanes by inducing the formation of H+, H-, and biatomic active hydrogen. (C) 2017 Elsevier Ltd. All rights reserved.
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