Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 13, Pages 1655-1658Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07591d
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Funding
- Scientific Research Fund Project of Hainan University [KYQD(ZR)1958]
- Young Technology Stars Project in Shaanxi Province of China [2018KJXX-048]
- State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute
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A palladium-catalyzed selective B(3)-H arylation of o-carboranes at room temperature has been developed, using readily available arylboronic acids as the aryl source. The method provides an efficient synthetic route for constructing polysubstituted o-carborane derivatives.
A palladium-catalyzed selective B(3)-H arylation of o-carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl-o-carboranes were obtained in good to excellent yields. This method provides a powerful synthetic route for constructing polysubstituted o-carborane derivatives.
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