Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 13, Pages 1611-1614Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07787a
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- Universita di Napoli Federico II [DR_409_2017]
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The mechanisms for the formation of syndiotactic PLA by the ROP of meso-LA using a chiral-Al complex are revealed through DFT calculations. Contributions towards stereoselectivity have been analyzed, confirming the importance of peculiar chiral recognition for stereocontrolled ROP polymerization.
The mechanism(s) for the formation of syndiotactic PLA by the ROP of meso-LA by a chiral-Al-complex are disclosed by DFT calculations. The contributions toward stereoselectivity have been analyzed confirming the peculiar chiral recognition for stereocontrolled ROP polymerization.
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