Journal
FUEL
Volume 200, Issue -, Pages 316-332Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2017.03.077
Keywords
Ionic liquid; Carbon dioxide; Dimethyl carbonate; Styrene carbonate (SC); Propylene carbonate; Cyclic carbonate; Catalytic system
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Funding
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning, Republic of Korea [2014R1A2A2A01004352]
- National Research Foundation of Korea [2014R1A2A2A01004352] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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In this review, primary focus on the ionic liquid (IL) catalysts and related catalytic systems for utilization of carbon dioxide to a production of linear as well as cyclic carbonate, and describes the innovative progress observed during last ten years. This review covers trend of various catalysts starting from first conventional ILs (tetrabutylammonium bromide and imidazolium IL) to the latest metal containing IL systems employed for the efficient production of dimethyl carbonate. Moreover, recent advances in DMC production also summarizes using the catalysts which contain novel super base facilitated tricationic IL systems. Similarly, cyclic carbonate synthesis reveals the benefits of using IL based catalyst on the verity of different supporting materials such as alumina, silica, carbon nanotubes, magnetic nanoparticles, poly(ethylene glycol), polystyrene, cellulose, and chitosan. The summary of ammonium, phosphonium and both functionalized and unfunctionalized imidazolium salts indicates that the turnover frequency for epoxide and propylene oxide enhances under mild reaction condition. Overall, it is clear that metal ions or super base in the combination of ILs can improve the conversions and the presence of hydroxyl, carboxyl, and other functional groups will enhance the yield multiple folds through hydrogen bonding interaction. (C) 2017 Elsevier Ltd. All rights reserved.
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