An environmentally benign post-polymerization functionalization strategy towards unprecedented poly(vinylamine) polyHIPEs

Interconnected highly porous poly(vinylamine) monoliths are produced by post-polymerization hydrolysis of emulsion-templated poly(N-vinylformamide) polyHIPEs (polymerized high internal phase emulsions). Unlike previous work, in which polyHIPEs were amine-functionalized only to a small extent, our approach includes the hydrolysis of the formyl groups of the highly porous poly(N-vinylformamide) monolith, resulting in an exceptionally high degree of amine-functionalization, i.e. up to 10 mmol of primary amine functional groups per gram or 12 mmol of nitrogen per gram of polyHIPE. Importantly, this post-polymerization functionalization strategy preserves the polyHIPE features, such as morphology, porosity and three-dimensional (3D) interconnectivity and is carried out without the use of hazardous organic solvents, toxic amine reagents or catalysts. The resulting poly(vinylamine)-polyHIPEs exhibit pH-responsive swelling and water absorption behaviour and prove to be promising candidates for metal ion capture. Overall, the reported post-functionalization strategy is attractive for the production of unprecedented, high-density, primary amine-functionalized 3D-interconnected porous organic foams, materials of great interest for further derivatization and use in numerous applications.

Automated summary

The study presents a method for producing interconnected highly porous poly(vinylamine) monoliths with a high degree of amine-functionalization through post-polymerization hydrolysis. This strategy preserves the features of polyHIPE and exhibits pH-responsive swelling and water absorption behavior, making the resulting poly(vinylamine)-polyHIPEs promising candidates for metal ion capture. The post-functionalization strategy is attractive for producing high-density, primary amine-functionalized 3D-interconnected porous organic foams with potential applications in various fields.