Understanding the structure, bonding and reactions of nanocrystalline semiconductors: a novel high-resolution instrumental method of solid-state synchronous luminescence spectroscopy

This Perspective Article describes the recent advancements in studies of nanocrystalline metal oxides using a novel ultra-high resolution method, solid-state synchronous luminescence spectroscopy (SS-SLS). Semiconductors notably include titanium dioxide and these studies shed light on the detailed electronic structure, composition, and their reactions. First, we critically discuss the limitations of the major existing non-spectroscopic and spectroscopic methods of characterization of electronic structure of nanocrystalline semiconductors and insulators. Second, we describe the foundations and the setup of SS-SLS as an enhanced-resolution, facile, non-contact, non-destructive, and highly capable method of studies of nanomaterials. Third, the following insights are featured which are obtained by SS-SLS, but are not available by other methods: (a) detection of traps of electric charge (specific mid-gap states); (b) discrimination between surface and bulk sites; (c) in situ studies of composite nanomaterials and mechanisms of reactions, (d) the derivative SS-SLS for accurate determination of energies of absorption and emission. The specific advantages of SS-SLS versus other methods and in direct comparison with conventional photoluminescence spectroscopy are highlighted. Finally, new opportunities and challenges of SS-SLS are presented. SS-SLS is an advanced spectroscopic method with significant potential to aid academia and industry in studies of chemo-sensing, photocatalysis, optoelectronic materials, applied surface science, development of instrumental analysis, and studies of mechanisms of surface and bulk chemical reactions.

Automated summary

SS-SLS is an advanced spectroscopic method that offers high resolution and various advantages for studying the electronic structure and reaction mechanisms of nanocrystalline metal oxides, particularly semiconductors including titanium dioxide. It provides insights such as detection of electric charge traps, discrimination between surface and bulk sites, in situ studies of composite nanomaterials, and accurate determination of absorption and emission energies which are not available by other methods. Additionally, SS-SLS shows specific advantages over conventional photoluminescence spectroscopy in terms of enhanced capabilities and resolution.