4.7 Article

A facile method for the synthesis of a sintering dense nano-grained Na3Zr2Si2PO12 Na+-ion solid-state electrolyte

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 33, Pages 4023-4026

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07261c

Keywords

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Funding

  1. National Natural Science Foundation of China [51702030, U1864208]
  2. Key Program for International Science and Technology Cooperation Projects of the Ministry of Science and Technology of China [2016YFE0125900]
  3. Fund for Innovative Research Groups of Natural Science Foundation of Hebei Province [A2020202002]
  4. National Science and Technology Major Project [2017-VII-0011-0106]

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Dense Na3Zr2Si2PO12 with an average grain size of 546 +/- 58 nm was reported, prepared using a facile method. The nano-grained Na3Zr2Si2PO12 showed extremely high conductivity and low interfacial resistance at 25 degrees C. Such processing enables the exploration of nanocrystalline conductors.
We report dense Na3Zr2Si2PO12 with an average grain size of 546 +/- 58 nm and prepared by a facile method. The nano-grained Na3Zr2Si2PO12 exhibits an extremely high conductivity of 1.02 x 10(-3) S cm(-1) and low interfacial resistance of 35 omega cm(2) at 25 degrees C. Such processing facilitates the exploration of nanocrystalline conductors.

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