Journal
ACS APPLIED POLYMER MATERIALS
Volume 3, Issue 2, Pages 1060-1069Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsapm.0c01307
Keywords
CMC/agar; cellulose nanocrystal; shikonin; antimicrobial; antioxidant; smart packaging film
Funding
- National Research Foundation of Korea (NRF) - Korea government (MSIT) [2019R1A2C2084221]
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A multifunctional carboxymethyl cellulose/agar-based smart film was fabricated using cellulose nanocrystals (CNC) from onion peel and shikonin from the roots of Lithospermum erythrorhizon. The film showed improved physical and functional properties, making it suitable for active food packaging applications.
Multifunctional carboxymethyl cellulose/agar-based smart films were fabricated combining cellulose nanocrystals (CNC) separated from onion peel and shikonin isolated from the roots of Lithospermum erythrorhizon. The CNC had a nanosized crystal structure with a length and width of 225.6 +/- 42.4 and 10.2 +/- 2.2 nm, respectively, having an aspect ratio of 22.1. The CNC and shikonin were consistently dispersed in the polymer matrix. The integration of CNC significantly improved physical properties, for instance, mechanical, water resistance, and optical properties. The addition of shikonin provided functional properties such as pH-responsive color change, antioxidant and antibacterial properties without significant change in the water vapor permeability, and thermal stability of the film. The films also exhibited high light transmittance with increased UV-light barrier properties. The composite film also showed potent antimicrobial and antioxidant activities. The composite film with enhanced physical and functional properties has high potential for quality detection in active food packaging applications.
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