Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 33, Pages 4055-4058Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc08359c
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Funding
- European Union (European Social Fund-ESF) [MIS 5048472]
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In this study, a covalently connected peptide-porphyrin hybrid was prepared and found to self-assemble into either spheres or fibrils depending on the solvent mixture. Photocatalytic hydrogen evolution experiments showed that fibrils were more efficient in H-2 production compared to spheres.
Herein, we illustrate the preparation of a covalent connected peptide-porphyrin hybrid (Fmoc-FF-(Zn)Por). The thorough investigation of its self-organization features demonstrated that Fmoc-FF-(Zn)Por self-assembles into either spheres or fibrils by altering the solvent mixture. Interestingly, photocatalytic hydrogen (H-2) evolution experiments revealed that fibrils were more efficient towards H-2 production compared to spheres.
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