Journal
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
Volume 9, Issue 2, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2021.105138
Keywords
Cuprous oxide; Photocatalysts; Photocorrosion; Semiconducting polymers
Categories
Funding
- Malaysia Ministry of Education (MOE) under the Higher Institution Centre of Excellence (HICoE) grant [R.J090301.7851.4J431]
- Fundamental Research Grant Scheme (FRGS) [FRGS/1/2018/STG07/UTM/02/3]
Ask authors/readers for more resources
Cuprous oxide is a semiconductor with characteristics of abundance, low toxicity, and easy synthesis, but faces challenges in photocorrosion, stability, and charge carrier recombination. Incorporating other materials to form composite photocatalytic materials is a viable strategy to enhance its performance.
Cuprous oxide (Cu2O) is a semiconductor with some interesting features, such as abundance in nature, low cost, low toxicity, and facile synthesis. It crystallizes in cubic structure and has a bandgap of 2.0-2.2 eV. Such a narrow bandgap renders it suitable as a visible-light photocatalyst. Nonetheless, the issues with photocorrosion, stability, and fast recombination of charge carriers restrict its application in photocatalysis. Although Cu2O is thermodynamically stable in air, it eventually degrades into copper(II) oxide in the presence of moisture and light. One viable strategy to enhance its stability against photocorrosion and to delay charge carrier recombination is to incorporate other materials to form composite photocatalytic materials. This review discusses the various methods used in improving the properties of Cu2O and the future outlook of this photocatalyst. The review begins with the basic structure, electronic and optical properties of Cu2O followed by the synthesis methods for preparing pristine and composite Cu2O photocatalysts as well as the strategies used in enhancing the photo catalytic performance of Cu2O. The promising applications in a wide range of photocatalytic reactions are summarized to illustrate its potential use. Finally, the challenges on the use of Cu2O photocatalysts are addressed as a concluding remark.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available