Journal
DALTON TRANSACTIONS
Volume 50, Issue 13, Pages 4499-4503Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt00289a
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Funding
- National Science Fund for Distinguished Young Scholars [21925603]
- National Natural Science Foundation of China [21836001, 22076186, 22076187, 11775037]
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Two complexes can be obtained based on the diverse secondary assembly of U4L4 cages by adjusting the carbon chain length of organic templates, and the mechanism of different arrangements of U4L4 cages induced by organic templates was explored in detail.
Herein, we report a new uranyl-organic polyhedron U4L4 (L = BTPCA) assembled from uranyl and a semirigid tritopic ligand. By adjusting the carbon chain length of organic templates, two complexes can be obtained based on the diverse secondary assembly of U4L4 cages. The mechanism of different arrangements of U4L4 cages induced by organic templates was explored in detail.
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