Journal
GREEN CHEMISTRY
Volume 23, Issue 5, Pages 2095-2103Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc00317h
Keywords
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Funding
- National Natural Science Foundation of China [21672047]
- State Key Laboratory of Urban Water Resource and Environment [2018DX02]
- Science and Technology Plan of Shenzhen [JCYJ20180306172044124]
- Natural Science Foundation of Guangdong [2020A1515010564]
- Guangdong Province Covid-19 Pandemic Control Research Fund [2020KZDZX1218]
- Starting up fund from Shenzhen Government
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The electrochemical system described in this study utilizes triethylamine as a sacrificial reductant, offering easy operation, sustainable conditions, and a wide substrate scope for breaking various types of bonds. The selectivity and capability of reduction can be conveniently switched by incorporating or removing alcohol as a co-solvent.
A general electrochemical system for reductive hydrodefunctionalization is described, employing the inexpensive and easily available triethylamine (Et3N) as a sacrificial reductant. This protocol is characterized by facile operation, sustainable conditions, and exceptionally wide substrate scope covering the cleavage of C-halogen, N-S, N-C, O-S, O-C, C-C and C-N bonds. Notably, the selectivity and capability of reduction can be conveniently switched by simple incorporation or removal of an alcohol as a co-solvent.
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