Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 32, Pages 3865-3868Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00563d
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Funding
- National Natural Science Foundation of China (NSFC) [21971134, 21631007, 21225103]
- State Key Laboratory of Natural and Biomimetic Drugs [K20160202]
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Novel Anderson-type polyoxomanganotungstate clusters with the beta-isomer structure have been successfully synthesized and monofunctionalized with derivatives of 1,3-propanediol via a one-pot strategy, showing unprecedented coordination activity as non-lacunary polyoxotungstate clusters, which could have potential in the future construction of POM-frameworks.
Novel Anderson-type polyoxomanganotungstate clusters with the beta-isomer structure, [{R1R2C(CH2O)(2)}(MnW6O22)-W-IV](6-), were synthesized and monofunctionalized with derivatives of 1,3-propanediol via a one-pot strategy, and show unprecedented coordination activity as non-lacunary polyoxotungstate clusters and could have potential in the future construction of POM-frameworks.
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