4.7 Article

Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(vi) centres of Ru(ii)-Mo(vi) dyads†

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 34, Pages 4142-4145

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00750e

Keywords

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Funding

  1. ERC [279599-FunctionalDyna]
  2. Swiss NSF [200021_172696]
  3. NCCR MUST of the Swiss NSF
  4. EPSRC [EP/J019666/1]
  5. International Max Planck Research School for Ultrafast Imaging and Structural Dynamics (IMPRS-UFAST)
  6. European XFEL
  7. Comunidad de Madrid
  8. Universidad Autonoma de Madrid through Beatriz Galindo research project [SI2/PBG/2020-00003]
  9. Spanish MICIU through RD project [PID2019-108678GB-I00]
  10. IMDEA-Nanociencia through Severo Ochoa Programme in RD [SEV-2016-0686]
  11. Polish NCN through SONATA BIS 6 grant [2016/22/E/ST4/00543]
  12. EPSRC [EP/J019666/1] Funding Source: UKRI
  13. Swiss National Science Foundation (SNF) [200021_172696] Funding Source: Swiss National Science Foundation (SNF)

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Photo-induced oxidation-enhancement in biomimetic bridged Ru(ii)-Mo(vi) photo-catalyst is unexpectedly photo-activated in ps timescales, where one-photon absorption generates an excited state activating both photo-oxidized and photo-reduced catalytic centres independently.
Photo-induced oxidation-enhancement in biomimetic bridged Ru(ii)-Mo(vi) photo-catalyst is unexpectedly photo-activated in ps timescales. One-photon absorption generates an excited state where both photo-oxidized and photo-reduced catalytic centres are activated simultaneously and independently.

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