Journal
COORDINATION CHEMISTRY REVIEWS
Volume 293, Issue -, Pages 187-210Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2014.12.010
Keywords
Mo(W)-Cu-S cluster; Heterometallic cluster; Coordination polymer; Tp and Tp*; P-N cluster
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Funding
- National Natural Science Foundation of China [21171124, 21271134, 21373142, 21401134]
- State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry [2015kf-07]
- Science and Technology Department of Jiangsu Province [BK20140307]
- Department of Education of Jiangsu Province [14KJB150023]
- Qin-Lan Project
- 333 Project of Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- SooChow Scholar Program of Soochow University
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This review summarizes the uses of Tp-and Tp*-based Mo(W) sulfido precursor compounds, namely, [Et4N][Tp*WS3] (P1), [Et4N][Tp*MoS(S-4)] (P2), [Et4N][TpMoS(S-4)] (P3) and [(Tp*WS2)(2)(mu-S-2)] (P4) for the assembly of a diverse class of heterometallic clusters, predominantly Mo(W)-Cu-S clusters. Some of these clusters also feature as building blocks for cluster-supported coordination polymers to achieve enhanced third-order nonlinear optical performances. (C) 2014 Elsevier B.V. All rights reserved.
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