Journal
COORDINATION CHEMISTRY REVIEWS
Volume 293, Issue -, Pages 327-356Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2014.05.031
Keywords
Metal-organic framework; Metal-organic polyhedron; Biomimetic chemistry; Metalloporphyrin; Catalysis
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Funding
- Center for Gas Separations Relevant - U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
- Hydrogen and Fuel Cell Program [DE-FC36-07G017033]
- Methane Opportunities for Vehicular Energy (MOVE) Program, an ARPA-e project [DE-AR0000249]
- Welch Foundation [A-1725]
- Texas A&M graduate merit fellowship
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Nature has evolved a great number of biological molecules which serve as excellent constructional or functional units for metal-organic materials (MOMs). Even though the study of biomimetic MOMs is still at its embryonic stage, considerable progress has been made in the past few years. In this critical review, we will highlight the recent advances in the design, development and application of biomimetic MOMs, and illustrate how the incorporation of biological components into MOMs could further enrich their structural and functional diversity. More importantly, this review will provide a systematic overview of different methods for rational design of MOMs with biomimetic features. Published by Elsevier B.V.
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