4.7 Article

Highly efficient self-trapped exciton emission in a one-dimensional face-shared hybrid lead bromide

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 20, Pages 2495-2498

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc08218j

Keywords

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Funding

  1. NSFC [21871167, 22075168]
  2. 1331 Project of Shanxi Province
  3. Science and Technology Innovation Project of Higher Education Institutions in Shanxi [2019L0451]
  4. SXNU Startup

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A new one-dimensional face-shared hybrid lead bromide with intrinsic broadband yellow-light emission has been obtained, surpassing previously reported similar materials. The investigation of the emission mechanism in this material opens up possibilities for discovering more exceptional light-emitting materials.
A new one-dimensional (1D) face-shared hybrid lead bromide of (2cepiH)PbBr3, which exhibits intrinsic broadband yellow-light emission with a quantum yield of 16.8% outperforming all previously reported 1D face-shared hybrid metal halides, is obtained. The origin of broadband emission and the coexistence of free excitons and self-trapped excitons are deeply investigated by variable-temperature photoluminescence spectra. Our work paves the way to discovering more wonderful light-emitting materials.

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