4.6 Article

MXene potassium titanate nanowire/sulfonated polyether ether ketone (SPEEK) hybrid composite proton exchange membrane for photocatalytic water splitting

Journal

RSC ADVANCES
Volume 11, Issue 16, Pages 9327-9335

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra09935j

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Funding

  1. Thammasat University [2/2018]
  2. NSTDA Research Chair Professor Grant [P-17-52536]

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The hybrid composite C-SPEEK proton exchange membrane exhibits good proton conductivity and ion exchange capacity at room temperature, and is capable of generating hydrogen gas under UV light irradiation. By incorporating MKT-NW nanowires, the efficiency of hydrogen gas production can be improved, making it a promising candidate for renewable energy applications in photocatalytic water splitting.
A cross-linked sulfonated polyether ether ketone (C-SPEEK) was incorporated with MXene/potassium titanate nanowire (MKT-NW) as a filler and applied as a proton exchange membrane for photocatalytic water splitting. The prepared hybrid composite PEM had proton conductivity of 0.0097 S cm(-1) at room temperature with an ion exchange capacity of 1.88 meq g(-1). The hybrid composite proton exchange membrane is a reactive membrane which was able to generate hydrogen gas under UV light irradiation. The efficiency of hydrogen gas production was 0.185066 mu mol within 5 h for 12% wt of MKT-NW loading. The results indicated that the MKT-NW/C-SPEEK membrane is a promising candidate for ion exchange with hydrogen gas evolution in photocatalytic water splitting and could be applied as a renewable source of energy to use in various fields of applications.

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