4.6 Article

Wetting of a solid surface by active matter

Journal

SOFT MATTER
Volume 17, Issue 9, Pages 2468-2478

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sm02008g

Keywords

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Funding

  1. Portuguese Foundation for Science and Technology (FCT) [PTDC/FIS-MAC/28146/2017, LISBOA-01-0145-FEDER-028146, CEECIND/00586/2017, UIDB/00618/2020, UIDP/00618/2020, IF/00322/2015]

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A lattice model was used to study repulsive active particles on a planar surface, with a rejection-free Kinetic Monte Carlo method employed. The model predicted a motility-induced phase separation and the coexistence of dense liquid-like and dilute vapour-like steady states. By introducing an ensemble analogous to a grand canonical ensemble, the formation and growth of a liquid film between solid surface and vapour phase were investigated.
A lattice model is used to study repulsive active particles at a planar surface. A rejection-free Kinetic Monte Carlo method is employed to characterize the wetting behaviour. The model predicts a motility-induced phase separation of active particles, and the bulk coexistence of dense liquid-like and dilute vapour-like steady states is determined. An ensemble, with a varying number of particles, analogous to a grand canonical ensemble in equilibrium, is introduced. The formation and growth of the liquid film between the solid surface and the vapour phase is investigated. At constant activity, as the system is brought towards coexistence from the vapour side, the thickness of the adsorbed film exhibits a divergent behaviour regardless of the activity. This suggests a complete wetting scenario along the full coexistence curve.

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