Journal
COORDINATION CHEMISTRY REVIEWS
Volume 297, Issue -, Pages 91-126Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.02.019
Keywords
Group 13 elements; Lewis superacids; Group 13 element trihalides; Donor-acceptor complexes; Metal-metal bond; Structure
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Funding
- St. Petersburg State University [12.37.139.2011, 12.38.255.2014]
- Alexander von Humboldt foundation
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In the present review recent advances in the chemistry of group 13 Lewis acids, such as intermolecular complexes with donor-acceptor metal-metal bonds, bifunctional Lewis acids and complexes of Lewis superacids, as well as selected examples of their application in different areas of chemistry are presented. Structural properties of molecular donor-acceptor complexes formed by strong group 13 element Lewis acids EX3 (E=B, Al, Ga; X=Cl, C6F5) with M,C,N,P,O,S-donor-ligands (M - main group or transition metal) are presented and changes in the geometry of the acceptor moiety upon complex formation are analyzed. (C) 2015 Elsevier B.V. All rights reserved.
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