4.8 Review

Transition metal-catalyzed alkene isomerization as an enabling technology in tandem, sequential and domino processes

Journal

CHEMICAL SOCIETY REVIEWS
Volume 50, Issue 2, Pages 1391-1406

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00449a

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Funding

  1. University of Geneva
  2. Swiss National Science Foundation [200020_175489, 200021_188490]
  3. Swiss National Science Foundation (SNF) [200021_188490, 200020_175489] Funding Source: Swiss National Science Foundation (SNF)

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This review covers the one-pot reactions centered around transition metal-catalyzed isomerization of alkenes, showcasing their advantages in atom, step, and redox economy, as well as the preparation of value-added products that are difficult to access through conventional methods.
One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not only offer the inherent advantages of atom-, step- and redox-economy but also enable the preparation of value-added products that would be difficult to access by conventional methods. In this Review, we cover seminal and recent examples of tandem, sequential and domino processes, which incorporate the most attractive features of olefin isomerization.

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