4.7 Article

A rechargeable aqueous proton battery based on a dipyridophenazine anode and an indium hexacyanoferrate cathode†

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 35, Pages 4307-4310

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01486b

Keywords

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Funding

  1. National Natural Science Foundation of China [21773018, 21975033]
  2. Foundation of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
  3. Qing Lan project of Jiangsu Province

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The rocking-chair aqueous proton battery utilizes dipyridophenazine and indium hexacyanoferrate as anode and cathode materials, achieving a reversible specific capacity of 37 mA h g(-1) at 1 A g(-1), good cycling stability with 76.1% capacity retention over 3000 cycles, and excellent rate capability.
A rocking-chair aqueous proton battery is assembled by using dipyridophenazine and indium hexacyanoferrate as the anode and cathode materials, respectively. The reversible amination of redox-active phenazine moieties in dipyridophenazine and fast intercalation-deintercalation of protons in hexacyanoferrate enable the aqueous proton battery to achieve a reversible specific capacity of 37 mA h g(-1) at 1 A g(-1), good cycling stability with 76.1% capacity retention over 3000 cycles and excellent rate capability.

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