Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 21, Pages 2665-2668Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00433f
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Funding
- National Natural Science Foundation of China [21702026]
- Fundamental Research Funds for the Central Universities [N2005004, N180705004]
- Baiqing project of Jiaxing University [CD70619010]
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A Ru(ii)-catalyzed coupling reaction has been developed for the synthesis of 1-naphthols in good to excellent yields. The transformation proceeds through Ru-catalyzed C-H activation of phosphoniums, Ru-carbene insertion, and intramolecular Wittig reaction processes.
A Ru(ii)-catalyzed coupling of various alpha-carbonyl phosphoniums with sulfoxonium ylides has been realized for the facile synthesis of 1-naphthols in good to excellent yields. This oxidant-free transformation proceeds through Ru-catalyzed C-H activation of phosphoniums, Ru-carbene insertion, and intramolecular Wittig reaction processes.
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