Journal
FOOD HYDROCOLLOIDS
Volume 67, Issue -, Pages 45-53Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.foodhyd.2016.12.040
Keywords
Carrageenan hydrogel; ZnO nanoparticles; CuO nanoparticles; Nanocomposite film; Antibacterial activity; UV-barrier
Categories
Funding
- Business for Cooperative R&D between Industry, Academy, and Research Institute - Korea Small and Medium Business Administration [C0297411]
- Korea Technology & Information Promotion Agency for SMEs (TIPA) [C0297411] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Carrageenan-based functional hydrogels and dry films were prepared by blending with metallic nano particles such as zinc oxide (ZnO), copper oxide (CuO) NPs, and their combination. Addition of KCI as a cross-linking agent increased the gel strength of carrageenan-based hydrogels. The neat carrageenan hydrogels were transparent, but they became translucent when the metallic nanoparticles were incorporated. Dried hydrogel films were flexible and free-standing. Transmission of UV light of the carrageenan-based films decreased remarkably when metallic NPs were incorporated. The swelling ratio (SR) of carrageenan films with or without cross-linker were 2980% and 2665%, respectively, however, it increased up to 3535% when ZnONPs were incorporated. The carrageenan-based hydrogel films with metallic nanoparticles exhibited strong antibacterial activity against food-bourne pathogenic bacteria, Escherichia coil, and Listeria monocytogenes. The ZnONPs incorporated hydrogel films exhibited higher mechanical, UV-screening, water holding, thermal stability, and antimicrobial properties than the CuONPs incorporated ones. The nanocomposite hydrogels or films have a high potential for the application in the biomedical, cosmetic, and active food packaging areas. (C) 2017 Elsevier Ltd. All rights reserved.
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