4.6 Review

Reactions of nickel(0) with organochlorides, organobromides, and organoiodides: mechanisms and structure/reactivity relationships

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 11, Issue 9, Pages 2980-2996

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cy00374g

Keywords

-

Funding

  1. AstraZeneca
  2. EPSRC [EP/R512114/1]
  3. University of Strathclyde

Ask authors/readers for more resources

The review focuses on the reactions of nickel(0) complexes with organohalides, categorized based on the type of ligand present on nickel. The preferred reaction mechanism is influenced by a delicate balance of ligand and substrate structure, with small changes potentially leading to significant behavioral differences. This will impact the advancement of catalytic reactions using organohalide substrates and may affect ligand selection and the scope and limitations of the reactions.
The reactions of nickel(0) complexes with organohalides have been reviewed. The review is divided according to the class of ligand that is present on nickel: phosphine, N-heterocyclic carbene, or bidentate nitrogen ligand. The preferred mechanism of reaction is often determined by a delicate balance of ligand and substrate structure, and relatively small changes can lead to large differences in behaviour. This will have an impact on the progress of catalytic reactions that use organohalide substrates, and may influence ligand selection and/or the scope and limitations of the reaction.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available